Bis{2,4-dibromo-6-[(2-phenylethyl)iminomethyl]phenolato-κ2 N,O}cobalt(II)
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چکیده
In the title complex, [Co(C(15)H(12)Br(2)NO)(2)], the Co(II) atom is four-coordinated by two N,O-bidentate chelate Schiff base ligands, displaying a flattened tetra-hedral coordination environment. The Co(II) atom occupies a special position on a twofold rotation axis. In the crystal, mol-ecules are linked via weak C-H⋯Br inter-actions.
منابع مشابه
Bis{2,4-dibromo-6-[(E)-(4-fluorobenzyl)iminomethyl]phenolato-κ2 N,O}cobalt(II)
The complete mol-ecule of the title complex, [Co(C(14)H(9)Br(2)FNO)(2)], is generated by crystallographic twofold symmetry, with the Co(II) atom lying on the rotation axis. The coordination of the metal atom by the two N,O-bidentate ligands results in a squashed CoN(2)O(2) tetra-hedron. The six-membered chelate ring is an envelope, with the metal atom as the flap. The dihedral angle between the...
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